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HASTELLOY B3
Hastelloy B3
Hastelloy B3 - 1

Hastelloy B3

UNS N10675W.Nr. 2.4600

Ultra-corrosion-resistant nickel-molybdenum superalloy for extreme reducing acid environments

Hastelloy B3 delivers unparalleled resistance to concentrated reducing acids including hydrochloric acid, phosphoric acid, and sulfuric acid at elevated temperatures. Engineered for mission-critical chemical processing and corrosive fluid handling where failure prevention is paramount.

Quick Specifications

UNS Designation
N10675
Werkstoff Number
2.4600
Form
Ingot, Plate, Rod, Bar, Tube, Wire
Tensile Strength (at 20°C)
690 - 860 MPa
Yield Strength (0.2% Offset)
310 MPa minimum
Elongation
20% minimum

Standards & Certifications

ASTM B 366 (Castings)ASTM B 619 (Rod and Bar)ASTM B 622 (Seamless Tube)ASME SB 619 (Rod/Bar)ASME SB 622 (Tube)DIN 17751 (Seamless Tubes)EN 10283 (High Nickel-Chromium Alloy Castings)
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Product Description

Hastelloy B3 is a proprietary nickel-molybdenum superalloy engineered specifically to provide the most comprehensive corrosion resistance available for aggressive reducing acid environments. The advanced composition with high molybdenum content, chromium for broader corrosion resistance, and tungsten for enhanced strength delivers exceptional immunity to attack by hydrochloric acid, phosphoric acid, sulfuric acid, and mixed acidic media at temperatures approaching the alloy's melting point. This material represents the ultimate solution for chemical processing applications where any corrosion failure would result in catastrophic consequences.

The microstructure is carefully controlled through vacuum induction melting and electroslag remelting to ensure absolute cleanliness and optimal distribution of alloying elements. The resulting material exhibits remarkable resistance to both uniform corrosion and localized attack phenomena that plague lower-grade materials. Every Hastelloy B3 ingot undergoes rigorous quality verification including impact testing, mechanical property sampling, and chemical composition analysis to guarantee compliance with the most stringent specifications.

Hastelloy B3 is available in plate, rod, bar, tube, and wire forms to accommodate diverse equipment fabrication requirements. The material exhibits excellent weldability, compared to competing exotic alloys, though specialized techniques and filler materials are essential. The superior strength retention at elevated temperatures, combined with exceptional corrosion resistance, enables designers to create compact, efficient equipment that maximizes production capacity while minimizing capital investment.

With an unmatched service history in the world's most demanding chemical processing applications, from concentrated acid synthesis to hazardous waste processing, Hastelloy B3 stands as the benchmark standard for engineers who require absolute assurance of material integrity. The alloy's documented performance in applications where alternative materials failed within days or weeks demonstrates its uncompromising ability to deliver long-term, trouble-free service.

Specifications

UNS DesignationN10675
Werkstoff Number2.4600
FormIngot, Plate, Rod, Bar, Tube, Wire
Tensile Strength (at 20°C)690 - 860 MPa
Yield Strength (0.2% Offset)310 MPa minimum
Elongation20% minimum
Density9.24 g/cm³
Melting Point1260 - 1290°C
Thermal Conductivity at 100°C10.6 W/m·K
Modulus of Elasticity228 GPa at 20°C
Maximum Service Temperature815°C (continuous)
Corrosion Rate in 6M HCl< 0.13 mm/year at 65°C

Chemical Composition

ElementContent (%)
Nickel (Ni)Remainder (min 47)
Molybdenum (Mo)28.0 - 32.0
Chromium (Cr)2.5 - 3.5
Tungsten (W)2.4 - 3.3
Iron (Fe)≤ 2.5
Cobalt (Co)≤ 2.5
Carbon (C)≤ 0.10
Manganese (Mn)≤ 1.5
Silicon (Si)≤ 1.0
Sulfur (S)≤ 0.030

Mechanical Properties

PropertyValue
Tensile Strength at 20°C690 - 860 MPa
Tensile Strength at 538°C480 - 620 MPa
Yield Strength (0.2% Offset) at 20°C310 MPa minimum
Yield Strength at 538°C240 MPa minimum
Elongation at 20°C20% minimum
Reduction of Area25% minimum
Hardness (As-cast)285 - 330 HV
Impact Strength (Charpy V)≥ 40 J at 20°C

Key Features & Advantages

Unparalleled resistance to concentrated reducing acids including HCl, H2SO4, and H3PO4
Superior corrosion resistance in wet chlorine and hydrogen chloride gas environments
Excellent strength retention at elevated temperatures up to 815°C continuous service
Outstanding weldability compared to other exotic nickel-molybdenum superalloys
Exceptional resistance to pitting and crevice corrosion in mixed acidic environments
Low thermal expansion enabling reliable service in thermal cycling applications
Proven reliability with decades of service in the world's most demanding applications
Available in multiple forms including castings, plate, bar, tube, and wire for flexible fabrication

Applications

Chemical Processing Equipment

Manufacturing of reactor vessels, agitator shafts, internal baffles, and condenser tubes for handling concentrated phosphoric acid, nitric acid, and sulfuric acid where material integrity is critical to operational safety.

Wet Chlorine Processing

Fabrication of equipment and piping for handling wet chlorine gas, hydrochloric acid vapors, and related products in chlor-alkali plants where corrosive environments would destroy conventional materials within hours.

Pharmaceutical and Fine Chemical Synthesis

Construction of reactor systems, distillation columns, and process equipment for specialty chemical synthesis where purity requirements and severe corrosive conditions demand superior material performance.

Aggressive Waste Treatment Systems

Manufacturing of waste acid neutralization equipment, contaminated water processing vessels, and hazardous waste disposal systems where extreme corrosive conditions and mixed media require material with unmatched durability.

Oil Refining and Hydroprocessing

Fabrication of heat exchangers, reactor internals, and fractionation equipment in hydrocracking and hydrotreating units where exposure to hydrogen, sulfur compounds, and acidic media demands superior material integrity.

Mineral Acid Production

Manufacturing of contact sulfuric acid coolers, phosphoric acid process equipment, and hydrochloric acid handling systems where direct exposure to concentrated acids at elevated temperatures challenges all but the most advanced alloys.

Frequently Asked Questions

Why is Hastelloy B3 preferred over Inconel 686 for concentrated acid service?
While Inconel 686 excels in seawater and chloride environments, Hastelloy B3's ultra-high molybdenum content provides superior resistance to reducing acids like hydrochloric, phosphoric, and sulfuric acids. Hastelloy B3 maintains excellent corrosion resistance in concentrated acid service where Inconel 686 corrodes at unacceptable rates.
What welding procedures are critical for maintaining Hastelloy B3 corrosion resistance?
Gas tungsten arc welding (GTAW) with compatible filler material (ERNiMo-10) and strict control of heat input and interpass temperature are essential. Post-weld annealing at 1040-1100°C followed by rapid cooling restores optimal corrosion resistance in the heat-affected zone.
Can Hastelloy B3 be machined, or must components be cast?
Both approaches are viable. While castings are suitable for complex shapes like reactor internals, machining from plate or bar enables precision components with superior cleanliness. Machining requires carbide tools, low speeds, appropriate cutting fluids, and patience due to the alloy's work-hardening characteristics.
What is the typical corrosion rate of Hastelloy B3 in 6M hydrochloric acid?
In boiling 6M hydrochloric acid, Hastelloy B3 exhibits corrosion rates typically less than 0.13 mm/year, essentially negligible for practical applications. This exceptional performance in the most aggressive reducing acid conditions demonstrates the alloy's unmatched suitability for HCl service.
Is Hastelloy B3 suitable for oxidizing acid environments like nitric acid?
Hastelloy B3 is specifically designed for reducing acids and performs poorly in oxidizing environments like concentrated nitric acid. For mixed or oxidizing acid service, higher-chromium alloys like Hastelloy C-276 or Inconel 686 provide superior performance.

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