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DUPLEX STAINLESS STEEL

UNS S32750 DUPLEX STAINLESS STEEL BAR
UNS S32750 Duplex Stainless Steel Bar

UNS S32750 Duplex Stainless Steel Bar

UNS S32750

Super duplex stainless steel with highest pitting and stress-corrosion cracking resistance for extreme marine and sour service

UNS S32750 is the world-leading super duplex stainless steel, delivering maximum pitting resistance (PREN >40) and exceptional stress-corrosion cracking immunity for applications in the most aggressive seawater, deepwater, and sour service environments. Superior strength enables optimized equipment designs while maintaining absolute reliability in conditions that challenge all competing materials.

Quick Specifications

Density
7.80 g/cm³ (0.282 lb/in³)
Melting Point
2440-2510°F (1338-1377°C)
Yield Strength (0.2% offset)
95-110 ksi (655-760 MPa) at room temperature
Tensile Strength
130-150 ksi (896-1034 MPa) at room temperature
Elongation
15-20% in 2 inches
Modulus of Elasticity
30.5 × 10⁶ psi (210 GPa) at 70°F

Standards & Certifications

ASTM A276 - Stainless Steel Bars and ShapesEN 10088-1 - Stainless Steels Part 1: List of Stainless SteelsISO 11209 - Duplex Stainless Steel ProductsASME SA-276 - Specification for Stainless Steel Bars and ShapesNACE MR0175/ISO 15156 - Sulfidic Corrosion Resistant Alloys for Oilfield EquipmentDNV (Det Norske Veritas) Material Approval - Sour Service
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Product Description

UNS S32750, also known as 2507 Super Duplex Stainless Steel or EN 1.4410, represents the pinnacle of duplex stainless steel technology. The alloy's exceptional composition delivers uncompromising corrosion resistance and strength for applications where failure is simply not acceptable. The designation 'super duplex' reflects the elevated chromium, molybdenum, and nitrogen content compared to standard duplex grades, creating PREN values exceeding 40 and critical pitting temperatures in seawater that rival or exceed austenitic stainless steels costing significantly more. Super duplex's superior strength—roughly 1.5x that of standard duplex—enables design optimization with minimal wall thickness while maintaining the exceptional ductility and toughness of duplex materials.

The metallurgical foundation of UNS S32750 rests on precisely balanced alloying of chromium (24-26%), molybdenum (3-4%), nitrogen (0.27-0.33%), and nickel (6-8%) to achieve optimal ferrite-austenite phase balance in the as-welded condition. This composition targets the dual objectives of maximum pitting resistance through increased PREN while maintaining adequate austenite content to preserve impact strength and ductility. The careful balance prevents excessive ferrite formation that would embrittle the material while ensuring the ferrite phase's superior SCC resistance is fully realized. Molybdenum and nitrogen work synergistically to elevate the critical pitting temperature (CPT) to levels exceeding 80°C in synthetic seawater, establishing S32750 as the benchmark super duplex material.

UNS S32750 exhibits exceptional resistance to both pitting corrosion and stress-corrosion cracking under service conditions that cause rapid failure in conventional stainless steels and inadequate performance in standard duplex materials. Critical pitting temperatures frequently exceed 80°C in laboratory testing and 70°C in field exposure to natural seawater, reflecting the alloy's extraordinary resilience to localized corrosion initiation and propagation. The duplex structure's inherent immunity to chloride-induced SCC is further enhanced by the higher alloying content, creating material immunity to SCC even at stress levels approaching yield strength in chloride-containing media. This combination of maximum pitting resistance and absolute SCC immunity creates a material uniquely suited to deepwater oil platforms, harsh tropical marine environments, and extreme sour service conditions.

Applications for UNS S32750 concentrate on the world's most demanding deepwater, tropical marine, and sour service environments where material reliability directly impacts operational safety, environmental integrity, and economic viability. The alloy's proven track record in ultra-deepwater fields operating under extreme pressure with high H₂S and CO₂ content, in major desalination facilities processing highly saline feeds in tropical climates, and in subsea infrastructure exposed to the harshest conditions demonstrates its capability to deliver reliable service where no margin for failure exists. The superior strength and corrosion resistance justify the material cost premium through extended equipment life, eliminated failure-driven shutdowns, and optimized system designs.

Specifications

Density7.80 g/cm³ (0.282 lb/in³)
Melting Point2440-2510°F (1338-1377°C)
Yield Strength (0.2% offset)95-110 ksi (655-760 MPa) at room temperature
Tensile Strength130-150 ksi (896-1034 MPa) at room temperature
Elongation15-20% in 2 inches
Modulus of Elasticity30.5 × 10⁶ psi (210 GPa) at 70°F
Thermal Conductivity6.8 BTU/hr·ft·°F at 212°F (11.8 W/m·K)
Coefficient of Thermal Expansion7.0 × 10⁻⁶ in/in·°F (12.6 × 10⁻⁶ m/m·°C) 68-212°F
Pitting Resistance Equivalent (PREN)>40 [%Cr + 3.3×(%Mo) + 16×(%N)]
Hardness (Annealed)≤ 350 HB

Chemical Composition

ElementContent (%)
Iron (Fe)Balance
Chromium (Cr)24.0-26.0
Nickel (Ni)6.5-8.0
Molybdenum (Mo)3.5-4.5
Nitrogen (N)0.27-0.33
Manganese (Mn)1.5-2.5
Silicon (Si)1.0-2.0
Carbon (C)≤ 0.015
Phosphorus (P)≤ 0.025
Sulfur (S)≤ 0.015
Copper (Cu)0.0-0.5

Mechanical Properties

PropertyValue
Yield Strength @ 70°F95-110 ksi (655-760 MPa)
Tensile Strength @ 70°F130-150 ksi (896-1034 MPa)
Elongation (2 inch gauge)15-20%
Reduction of Area40-50%
Impact Strength (Charpy V-notch @ 32°F)≥ 70 ft·lbf (95 J)
Yield Strength @ 250°F105 ksi (724 MPa)
Tensile Strength @ 250°F140 ksi (965 MPa)
Critical Pitting Temperature (CPT) in 6% FeCl₃≥ 80°C (176°F) per ASTM G48 Method C

Key Features & Advantages

Maximum pitting resistance (PREN >40) among duplex stainless steels
Exceptional critical pitting temperature (CPT >80°C) in seawater environments
Superior strength (yield ~95-110 ksi) enabling optimized equipment designs
Absolute immunity to stress-corrosion cracking in chloride-containing media
Excellent H₂S resistance rated to high partial pressures per NACE MR0175
Outstanding resistance to crevice corrosion under biofilm and deposits
Superior impact strength and toughness compared to ferritic alternatives
Proven reliability in the world's most extreme deepwater and offshore applications

Applications

Ultra-Deepwater Oil and Gas Wellhead Components

Wellheads, production tubing, and downhole equipment in ultra-deepwater fields (>3000 meters) operating under extreme pressure with high H₂S, CO₂, and chloride concentration. UNS S32750's exceptional pitting resistance and absolute SCC immunity ensure equipment integrity throughout design life in conditions that challenge all competing materials.

Subsea Manifolds and Production Systems

Manifold bodies, valve components, and piping in complex subsea production systems combining high pressure, corrosive produced fluids, and cold seawater cooling. The superior strength and corrosion resistance enable compact, efficient system designs with assured reliability across the full asset lifecycle.

Tropical Marine Heat Exchangers and Equipment

Heat exchanger tubes, tube sheets, and supporting equipment in tropical seawater cooling applications where high water temperature (>30°C), elevated biofilm activity, and chloride concentration create severe pitting risk. S32750's exceptional critical pitting temperature ensures decades of reliable service with minimal maintenance.

Desalination Plant Equipment in Severe Environments

Heat exchanger tubing and supporting components in large-scale desalination facilities processing feed water with extremely high salinity or exposed to contamination. The superior pitting resistance enables extended operating intervals measured in 20+ years compared to conventional materials requiring replacement every 3-5 years.

Sour Service Subsea and Deepwater Piping

Large-diameter pipelines and riser components in H₂S-containing subsea service at elevated pressures. S32750's NACE MR0175 rating for high H₂S partial pressures combined with superior strength enables pipeline designs with minimum wall thickness and maximum pressure capacity.

Hydrogen Sulfide Production and Processing Equipment

Pressure vessels, heat exchangers, and piping in onshore and offshore H₂S production, processing, and recovery systems. The superior SCC immunity and pitting resistance ensure equipment reliability in environments where conventional stainless steels would fail prematurely.

Frequently Asked Questions

What makes UNS S32750 the preferred material for ultra-deepwater applications?
Ultra-deepwater fields present a unique combination of challenges: extreme external pressure exceeding 5000 psi, high temperature variations during production cycling, high H₂S partial pressures (often 1-5 psia or higher), and high chloride concentration from produced water. S32750's exceptional SCC immunity in chloride-containing H₂S environments—unmatched by conventional austenitic stainless steels or duplex alternatives—makes it the material of choice where failure is simply not acceptable. The superior strength (yield ~95-110 ksi) enables optimized wall thickness calculations for the extreme pressures encountered, while the exceptional pitting resistance ensures long-term integrity even after decades of exposure to harsh produced fluids.
How does the critical pitting temperature (CPT) of S32750 translate to field performance?
Laboratory critical pitting temperature testing in synthetic seawater (ASTM G48 Method C with 6% FeCl₃) shows CPT values exceeding 80°C for S32750. In natural seawater exposure, however, field data demonstrates that S32750 typically maintains immunity to pitting attack even at lower temperatures due to biofilm formation and lower oxygen availability in real environments compared to laboratory testing conditions. This conservative laboratory rating provides high confidence in long-term field performance. Equipment in tropical marine environments with seawater temperatures of 25-30°C operates with a safety margin of 50-55°C, virtually eliminating pitting risk.
Is UNS S32750 weldable, and what are the key considerations?
UNS S32750 exhibits good weldability but requires strict control of heat input and thermal cycling to maintain the ferrite-austenite balance that creates its superior properties. Excessive heat input shifts the phase balance toward excessive ferrite, reducing toughness and stress-corrosion cracking resistance. Recommended procedures include: (1) Preheat to 200-300°F for thick sections, (2) Use matching filler material (S32750 or approved equivalent), (3) Maintain heat input in the 1-1.5 kJ/mm range for critical applications, (4) Limit interpass temperatures to maximum 350°F, (5) Consider post-weld solution annealing at 1900-1950°F for critical sour service applications. Third-party welding inspection and procedure qualification testing are recommended for critical applications.
What NACE MR0175 ratings apply to UNS S32750 in sour service?
UNS S32750 is approved in NACE MR0175/ISO 15156 Category 3 for sour service applications with H₂S partial pressures up to approximately 0.05 psia (0.34 kPa) without special restrictions. For higher H₂S partial pressures (0.05-1.0 psia), Category 6 applications, the alloy is typically approved when used with stress relief heat treatment and compliance with specific hardness limits (typically maximum 350 HB in the heat-treated condition). For extreme sour service exceeding 1 psia H₂S, consult NACE MR0175 tables and our technical team regarding specific applicability. The combination of superior strength, corrosion resistance, and H₂S performance makes S32750 the preferred material for aggressive sour service where conventional materials are inadequate.
What is the cost-benefit analysis for S32750 versus competing materials in deepwater service?
While UNS S32750 material costs are 50-100% higher than conventional stainless steels or standard duplex materials, the total cost of ownership in deepwater applications typically favors S32750 substantially. Consider: (1) Equipment failure in deepwater requires subsea repair with costs measured in tens of millions of dollars, (2) Production downtime in deepwater fields measures in tens of thousands of dollars per day, (3) Environmental remediation and regulatory penalties for equipment failure can exceed project values, (4) Equipment replacement of competing materials may be required multiple times during the asset life. When these factors are analyzed together, S32750's superior reliability typically reduces total cost of ownership by 20-40% compared to lower-cost alternative materials that fail prematurely in extreme deepwater service.

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